Depends on the vehicle make, model, year. The "factory service manual" for the vehicle will have schematics and descriptions of the various EVAP systems, parts, and their operation.
Depending on operating conditions the tank vent is either open to atmosphere or shunted to a charcoal canister for vapor storage. During steady state driving conditions over about 30 mph the purge valve opens, the canister vent to atmosphere opens, and the intake vacuum draws fresh air through the charcoal canister, purging the stored fuel vapor for burning with the normal intake fuel/air mixture - it doesn't take long - maybe 30 seconds to a minute. The purge is done when the small extra air added to the intake mixture will not affect driveability.
Some years of the Escalade/GMC/Chevy truck series had real troubles with the charcoal retainer screens in the canister breaking and allowing charcoal granules into the vent/purge lines. Charcoal granules got sucked/blown throughout the entire pressure/vacuum system, causing all sorts of fuel fill and trouble code problems.