The thermostat is at the engine side of the lower radiator hose, but I doubt that's your problem. Get a block test kit from Napa or rent one from Autozone and test the surge tank for exhaust gases in the coolant.
P.S. You posted in the "Tech Tips" section. I'll move this to the Deville forum for you.
P.S. You posted in the "Tech Tips" section. I'll move this to the Deville forum for you.